| BIODEGRADABLE PLASTICS | | | | polyhydroxyalkonoates as energy storage |
| - TRANSGENIC PLANTS PROVIDING A | | | | compounds, some of the PHA polymers are |
| SOLUTION | | | | commercially valuable as biodegradable plastics. |
| Almost every | | | | Polyhyroxybutyrate is a |
| product we buy most of the food we eat and | | | | PHA produced in Ralstonia eutropha via three |
| many of the liquids we drink come encased in | | | | enzyme bio synthetic pathway consisting of ? |
| plastic packaging, which provides excellent | | | | – ketothiolase, aceto acetyl Co-A reductase, |
| protection for the product. It is cheap to | | | | and PHB synthase. PHB synthase production in |
| manufacture and seems to last forever. Lasting | | | | plants was first demonstrated in transgenic |
| forever, however, is proving to be a major | | | | Arabidopsis thaliana. Polyhydroxy alkanoates |
| environmental problem. Plastics are manufactured | | | | (PHAs), e.g., polyhydroxybutyrate (PHB), are |
| from numerous non-renewable resources like | | | | synthesized from acetyl-CoA used as precursor, |
| natural gas, coal, and oil. Plastics cannot be | | | | and are used for the synthesis of biodegradable |
| degraded easily in the natural environment due to | | | | plastics with thermoplastic properties. At present, |
| their long polymer molecules which are too large | | | | PHAs are produced by bacterial fermentation, and |
| and too tightly | | | | the cost of biodegradable plastic is substantially |
| | | | | higher than that of synthetic plastics. |
| A type of sturdy and | | | | Attempts are being |
| hard plastic is made with a molecule known as | | | | made to produce PHAs in transgenic plants to |
| Bisphenol A, BPA. BPA like many other man made | | | | reduce the cost. Genes encoding the two |
| chemicals is now detectable in most people’s | | | | enzymes, aceto-acetyl-CoA reductase (PhbB) and |
| blood streams and could cause dangerous | | | | PHB synthase (phbC), involved in the PHB |
| hormonal changes in children. BPA may tend to | | | | synthesis from the precursor acetyl-CoA have |
| cause cancer, early puberty, obesity and even | | | | been transferred from the bacterium Alcaligenes |
| attention deficit disorder. | | | | eutrophus and expressed in Arabidopsis thaliana. |
| To overcome this | | | | When the two enzymes were targeted into the |
| problem BIODEGRADABLE PLASTICS have been | | | | plastids, PHB accumulated in leaves. PHB |
| developed which are made from renewable | | | | production by transgenic plants provides an |
| resources, such as plants. Biodegradable plastics | | | | example of a novel compound synthesized in |
| are made with plant-based materials and result in | | | | plants. |
| 15% less carbon emission. Infact biodegradable | | | | Standards that certify biodegradability and |
| plastics have not been successful in replacing the | | | | compostability, |
| wide spread use of traditional petrochemical | | | | Following international organizations have |
| plastics. | | | | established standards and testing methods for |
| The following are few items and the time required | | | | compostability: American Society for Testing and |
| for their decomposition, | | | | Materials ASTM ASTM 6400-99 |
| Tin cans- 50 to 100 years | | | | European Standardization Committee (CEN) |
| Aluminum Cans- 80 to 100 years | | | | EN13432 |
| Glass Bottles- 1 million years | | | | International Standards Organization (ISO) |
| Newspapers- 25 to 50 years | | | | ISO14855 (only for biodegradation) |
| Polystyrene- 1000's of years | | | | German Institute for Standardization (DIN) DIN |
| Plastic bags- 400 years | | | | V49000 |
| So now we know the raising alarm being caused | | | | The ASTM, CEN and |
| in the environment by the use of plastics. But a | | | | DIN standards specify the criteria for |
| solution is always there, | | | | biodegradation, disintegration and eco-toxicity for |
| "Green Film" Plastic Bags and Products- 9 | | | | a plastic to be called compostable. While ISO |
| months to 5 years . | | | | 14855 makes no stipulations regarding |
| The plastics that are | | | | disintegrations or toxins remaining. |
| decomposed in the natural environment are | | | | Dealing with plastic |
| known as the “biodegradable plastics”. | | | | wastes has taken on significance not far short of |
| (‘Biodegradable’ means that a substance | | | | ultimate redemption. Developing biodegradable |
| can naturally decompose with the help of micro | | | | plastics is just one of the solutions to the existing |
| organisms and will not persist in the environment | | | | problem. Its our responsibility to remember that |
| beyond a certain period of time). The chemical | | | | by the uncontrolled use of plastics we are |
| bonds of biodegradable compounds are easily | | | | contributing our share to a deadly pollution whose |
| destroyed by a variety of bacteria over a small | | | | ill effects are irreversible and capable of reaching |
| period of time to facilitate their decomposition. As | | | | out to numerous generation to come. |
| early as in the year 1926, Lemoigne managed to | | | | REFERENCES |
| isolate the first of the polyhydroxyalkanoates | | | | 1. Nature journal, Nature Biotechnology. |
| – polyhydroxybutyrate (a homopolymer | | | | 2.Crop science journal. |
| whose building unit is the 3-hydroxybutyric acid) | | | | 3. India Together, Science and environment and |
| from the Bacillus megaterium bacterium. At the | | | | environmental plastics. |
| end of the 1950s, the presence of the | | | | 4. Australian Academy of Science. |
| polyhydroxybutyrate was confirmed as an energy | | | | 5. Eco Greenwares. |
| and carbon source and storage in many other | | | | 6. abc NEWS – Health |
| bacteria. Many species of bacteria accumulate | | | | 7. |